CSEC CHEMISTRY · EXAM PREPARATION · LESSON X6

Paper 032 Practice Paper 2: Qualitative Analysis, Salt Preparation and Electrolysis

A second full 40-mark Paper 032 style practice paper with three questions — identifying an unknown salt, preparing copper(II) sulfate crystals, and electrolysis of copper(II) sulfate — with marks tagged for experimental skills and use of knowledge.

Papers 1, 2 and 3Paper 032≈ 60 min
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

4 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON X6 · EXPLAINER

Paper 032 Practice Paper 2: Qualitative Analysis, Salt Preparation and Electrolysis

Another forty marks, another three practicals. This paper tests the skills teachers look for in the SBA: reporting observations, preparing a pure salt and measuring electrolysis.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Paper plan

3 questions; 40 marks: Q1 14, Q2 13, Q3 13.

Profiles

Experimental Skills [XS] 30; Use of Knowledge [UK] 10.

Q1 Analysis

Observation, inference; ionic equations; acid before barium.

Q2 Salt

Insoluble base in excess; filter; crystallise; dry.

Q3 Electrolysis

Cathode gains copper; anode loses; constant current.

Table

Quantity and unit in every heading.

Time

2 h 10 min: about 3 minutes per mark.

Self-marking

Tick each point you earned and note missed skills.

EXAM TIPS & COMMON MISTAKES

  • Record the exact colour and say whether the precipitate dissolves in excess.
  • For salt preparation, explain WHY the solid is added in excess.
  • Do not evaporate to dryness; use the crystallisation point test.
  • State a precaution and the reason for it.
Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Practice paper

1. The three questions in this practice paper are worth

Answer: B. Q1 14, Q2 13, Q3 13 = 40.
Syllabus C 6.1

2. A dirty green precipitate with NaOH that turns brown on standing indicates

Answer: C. Fe(OH)₂ oxidises to Fe(OH)₃.
Syllabus C 6.2

3. Acid is added before barium chloride when testing for sulfate in order to

Answer: D. Otherwise they give false white precipitates.
Syllabus A 7.7

4. The excess solid copper(II) oxide is removed by

Answer: A. Insoluble solid.
Syllabus A 7.4

5. Copper(II) oxide reacts with dilute sulfuric acid to give

Answer: B. Base + acid → salt + water.
Syllabus A 9.6

6. At the cathode during electrolysis of copper(II) sulfate with copper electrodes

Answer: C. Cu²⁺ + 2e⁻ → Cu.
Syllabus A 9.8

7. During electrolysis of copper(II) sulfate with copper electrodes, the blue colour

Answer: D. Copper ions removed at the cathode are replaced at the anode.
Syllabus · Skills

8. Evaporating a salt solution to dryness is avoided because

Answer: A. Crystallise on cooling instead.
Step 4 · Apply

Mock paper — self-marked

Write full answers, then reveal the mark scheme and tick the points you earned (40 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 032 practice · Question 1: Qualitative analysis (14 marks: [XS] 10, [UK] 4)

Question 1 [14 marks]

Solid A is a pale green crystalline salt which dissolves in water. When dilute sodium hydroxide is added dropwise to a solution of A, a dirty green precipitate forms which does not dissolve in excess and turns brown on standing. When dilute hydrochloric acid and barium chloride solution are added to another portion, a white precipitate forms.

(a) (a) Describe how the cation test with sodium hydroxide should be carried out. [4]

MARK SCHEME — (a) (max 4)

(b) (b) Draw a table with suitable headings for recording the tests. [3]

MARK SCHEME — (b) (max 3)

(c) (c) State three safety precautions for these tests. [3]

MARK SCHEME — (c) (max 3)

(d) (d) Identify the cation and anion in A. [2]

MARK SCHEME — (d) (max 2)

(e) (e) Write the ionic equation for the formation of the green precipitate. [1]

MARK SCHEME — (e) (max 1)

(f) (f) Explain why dilute acid is added before barium chloride in the test for sulfate. [1]

MARK SCHEME — (f) (max 1)

Paper 032 practice · Question 2: Preparing a salt (13 marks: [XS] 10, [UK] 3)

Question 2 [13 marks]

A student prepares pure dry crystals of copper(II) sulfate from copper(II) oxide and dilute sulfuric acid.

(a) (a) Describe the method, including a labelled diagram of the filtration stage. [6]

MARK SCHEME — (a) (max 6)

(b) (b) State why the copper(II) oxide is added in excess. [1]

MARK SCHEME — (b) (max 1)

(c) (c) State three precautions or steps to obtain pure, dry crystals. [3]

MARK SCHEME — (c) (max 3)

(d) (d) Write an equation for the reaction. [1]

MARK SCHEME — (d) (max 1)

(e) (e) State the colour of the solution and of the crystals. [1]

MARK SCHEME — (e) (max 1)

(f) (f) Name the type of reaction between an oxide and an acid. [1]

MARK SCHEME — (f) (max 1)

Paper 032 practice · Question 3: Electrolysis of copper(II) sulfate (13 marks: [XS] 10, [UK] 3)

Question 3 [13 marks]

A student electrolyses copper(II) sulfate solution using copper electrodes at a constant current. The mass of the cathode is 1.20 g at the start and 1.36, 1.52, 1.68 and 1.84 g after 5, 10, 15 and 20 minutes.

(a) (a) Describe how the student sets up the apparatus and obtains the readings. [5]

MARK SCHEME — (a) (max 5)

(b) (b) Draw a table with suitable headings for the results. [2]

MARK SCHEME — (b) (max 2)

(c) (c) State what should be plotted and the shape of the graph. [3]

MARK SCHEME — (c) (max 3)

(d) (d) Write the half-equation for the reaction at the cathode. [1]

MARK SCHEME — (d) (max 1)

(e) (e) Describe what happens at the anode and to the colour of the solution. [1]

MARK SCHEME — (e) (max 1)

(f) (f) Calculate the mass of copper deposited in 20 minutes. [1]

MARK SCHEME — (f) (max 1)

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Sources

Syllabus sources and past papers

Everything in this lesson is based on these parts of the CXC syllabus and papers.