CSEC CHEMISTRY · EXAM PREPARATION · LESSON X5

Paper 032 Practice Paper 1: Titration, Rates and Conductivity

A full 40-mark Paper 032 style practice paper with three questions — acid–base titration, rate of reaction, and an investigation of conductivity — with marks tagged for experimental skills and use of knowledge.

Papers 1, 2 and 3Paper 032≈ 60 min
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

4 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON X5 · EXPLAINER

Paper 032 Practice Paper 1: Titration, Rates and Conductivity

Forty marks, three practical questions. Work through this paper in writing, as you would in the examination hall, then self-mark it against the scheme.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Paper plan

3 questions; 40 marks: Q1 14, Q2 13, Q3 13.

Profiles

Experimental Skills [XS] 30; Use of Knowledge [UK] 10.

Q1 Titration

n = C × V; ratio; mean of concordant titres.

Q2 Rate

Gas syringe; volume against time; rate is the gradient.

Q3 Conductivity

Strong electrolyte: more ions, brighter bulb.

Table

Quantity and unit in every heading.

Time

2 h 10 min: about 3 minutes per mark.

Self-marking

Tick each point you earned and note missed skills.

EXAM TIPS & COMMON MISTAKES

  • Draw a labelled diagram wherever the question asks for a method.
  • Check each table heading has a unit.
  • In calculations, write the formula and the unit of the answer.
  • Add one specific precaution and one specific source of error to each practical.
Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Practice paper

1. The three questions in this practice paper are worth

Answer: C. Q1 14, Q2 13, Q3 13 = 40.
Syllabus A 7.11

2. In a titration, 24.50 cm³ of 0.100 mol/dm³ HCl neutralises 25.0 cm³ of NaOH. The moles of HCl used are

Answer: D. 0.100 × 24.50 ÷ 1000.
Syllabus A 7.10

3. The indicator for a strong acid–strong alkali titration could be

Answer: A. Either works for strong acid–strong base.
Practice paper

4. A gas syringe measures the

Answer: B. Volume in cm³.
Syllabus A 8

5. The rate of reaction at any time is the

Answer: C. Rate = change in volume ÷ change in time.
Syllabus A 7.3

6. In the conductivity experiment, a brighter bulb for 0.1 mol/dm³ HCl than for 0.1 mol/dm³ ethanoic acid shows

Answer: A. Strong acid, more ions.
Syllabus A 9

7. Carbon electrodes are used in conductivity tests because they are

Answer: D. They do not react.
Syllabus · Skills

8. A burette reading is taken at the

Answer: A. Avoids parallax.
Step 4 · Apply

Mock paper — self-marked

Write full answers, then reveal the mark scheme and tick the points you earned (40 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 032 practice · Question 1: Titration (14 marks: [XS] 10, [UK] 4)

Question 1 [14 marks]

A student titrates 25.0 cm³ portions of sodium hydroxide solution with 0.100 mol/dm³ hydrochloric acid, using methyl orange. The rough titre is 25.20 cm³. The accurate titres are 24.90, 24.50 and 24.50 cm³.

(a) (a) Describe, with a labelled diagram, how the student should carry out the titration. [5]

MARK SCHEME — (a) (max 5)

(b) (b) Draw a table with suitable headings for the titration results. [3]

MARK SCHEME — (b) (max 3)

(c) (c) State which titres should be used for the mean titre and calculate it. [2]

MARK SCHEME — (c) (max 2)

(d) (d) Calculate the moles of hydrochloric acid used and state the moles of sodium hydroxide, given that NaOH + HCl → NaCl + H₂O. [2]

MARK SCHEME — (d) (max 2)

(e) (e) Calculate the concentration of the sodium hydroxide solution in mol/dm³. [2]

MARK SCHEME — (e) (max 2)

Paper 032 practice · Question 2: Rate of reaction (13 marks: [XS] 10, [UK] 3)

Question 2 [13 marks]

A student reacts magnesium ribbon with excess 1.0 mol/dm³ hydrochloric acid and collects the hydrogen in a gas syringe. The volume of gas is 0, 24, 40, 50, 56, 59 and 60 cm³ at times 0, 30, 60, 90, 120, 150 and 180 s.

(a) (a) Describe how the student collects and measures the gas. [5]

MARK SCHEME — (a) (max 5)

(b) (b) Draw a table with suitable headings for the results. [2]

MARK SCHEME — (b) (max 2)

(c) (c) State how the results should be plotted and what the graph will look like. [3]

MARK SCHEME — (c) (max 3)

(d) (d) State when the rate is fastest and give a reason. [1]

MARK SCHEME — (d) (max 1)

(e) (e) Explain why the total volume of gas is 60 cm³. [1]

MARK SCHEME — (e) (max 1)

(f) (f) State the effect of using warmer acid on the rate and the final volume. [1]

MARK SCHEME — (f) (max 1)

Paper 032 practice · Question 3: Conductivity of acids (13 marks: [XS] 10, [UK] 3)

Question 3 [13 marks]

A student wants to compare the electrical conductivity of 0.1 mol/dm³ hydrochloric acid and 0.1 mol/dm³ ethanoic acid.

(a) (a) Write a hypothesis and an aim for the investigation. [2]

MARK SCHEME — (a) (max 2)

(b) (b) List the apparatus and materials needed. [2]

MARK SCHEME — (b) (max 2)

(c) (c) Describe the method. [3]

MARK SCHEME — (c) (max 3)

(d) (d) Identify the manipulated variable, the responding variable and the controlled variables. [3]

MARK SCHEME — (d) (max 3)

(e) (e) Predict the result and explain it. [2]

MARK SCHEME — (e) (max 2)

(f) (f) State why carbon electrodes are used. [1]

MARK SCHEME — (f) (max 1)

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Sources

Syllabus sources and past papers

Everything in this lesson is based on these parts of the CXC syllabus and papers.