CSEC CHEMISTRY · SECTION B · LESSON B3

Reactions of Alkanes and Alkenes

Combustion and substitution of alkanes, addition reactions of alkenes (hydrogenation, halogenation, hydration), the test for unsaturation, and how the properties of hydrocarbons relate to their uses.

Organic ChemistryB 3.1B 3.2B 3.3B 3.4≈ 55 min🎮 3 games
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

5 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON B3 · EXPLAINER

Reactions of Alkanes and Alkenes

Alkanes like methane are quite unreactive, yet alkenes react readily. The reason is a single extra bond: the C=C double bond.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Explore in 3D

Alkanes and alkenes in 3D

Compare a saturated alkane with the planar C=C double bond of an alkene.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Combustion

Complete: CO₂ + H₂O; incomplete: CO / C + H₂O.

Alkanes

Saturated; unreactive; substitution with halogens in UV light.

Alkenes

Unsaturated; addition reactions.

Hydrogenation

Ni, ~150 °C.

Halogenation

Br₂ decolourised at room temperature.

Hydration

Steam, H₃PO₄, ~300 °C, 60 atm → ethanol.

Test for C=C

Bromine water decolourised; acidified KMnO₄ purple → colourless.

Uses

Alkanes: fuels, solvents; alkenes: polymers, alcohols.

EXAM TIPS & COMMON MISTAKES

  • Always state the CONDITIONS with the equation (UV light; Ni and 150 °C; steam, catalyst, 300 °C, 60 atm).
  • Substitution (alkanes) gives TWO products; addition (alkenes) gives ONE product.
  • The test needs the colour change of the reagent (orange → colourless), not just “it reacts”.
  • Burning is not acceptable as a test for unsaturation.
Play & practise

Games

3 quick games on this lesson. Earn XP and badges as you play — your best score for each game is saved. Games are for practice and do not change your exam readiness. More games in the Chemistry Arcade.

Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Syllabus B 3.1

1. The products of complete combustion of a hydrocarbon are

Answer: B. Plenty of oxygen.
Syllabus B 3.1

2. The reaction of methane with chlorine in ultraviolet light is

Answer: C. A hydrogen atom is replaced.
Syllabus B 3.1

3. Ethene reacts with bromine to give

Answer: D. Addition across the double bond.
Syllabus B 3.1

4. Ethene + steam → ethanol is called

Answer: A. Water is added.
Syllabus B 3.3

5. Which test distinguishes an alkene from an alkane?

Answer: B. Alkenes decolourise bromine water.
Syllabus B 3.2

6. Alkanes are described as saturated because they

Answer: C. No double bonds.
Syllabus B 3.1

7. Margarine is made from vegetable oils by

Answer: A. Hydrogen adds to C=C using a nickel catalyst.
Syllabus B 3.4

8. Alkenes are used mainly to make

Answer: D. They are the monomers.
Step 4 · Apply

Paper 2 practice — structured questions

Write full answers, then reveal the mark scheme and tick the points you earned (16 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 2 style · Alkanes and alkenes

Question 1 [16 marks]

Propane, C₃H₈, and propene, C₃H₆, are hydrocarbons.

(a) (a) Write a balanced equation for the complete combustion of propane. [2]

MARK SCHEME — (a) (max 2)

(b) (b) State two products of incomplete combustion of propane. [2]

MARK SCHEME — (b) (max 2)

(c) (c) Describe a chemical test to distinguish propane from propene, stating the observations. [3]

MARK SCHEME — (c) (max 3)

(d) (d) Write equations for the reactions of propene with (i) hydrogen and (ii) bromine, and name the type of reaction. [4]

MARK SCHEME — (d) (max 4)

(e) (e) Write an equation for the reaction of methane with chlorine and state the condition and type of reaction. [3]

MARK SCHEME — (e) (max 3)

(f) (f) State one use of alkanes and one of alkenes. [2]

MARK SCHEME — (f) (max 2)

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Sources

Where this topic appears in CSEC papers

Find these in your own past-paper booklets for extra timed practice. Items above are written in the style of these papers; any adapted from a specific question say so.