CSEC CHEMISTRY · SECTION B · LESSON B2

Organic Chemistry: Homologous Series, Formulae, Naming and Isomers

How carbon forms four bonds, writing molecular, condensed and fully displayed formulae, the characteristics of a homologous series, IUPAC names up to six carbons, and structural isomerism.

Organic ChemistryB 2.1B 2.2B 2.3B 2.4B 2.5B 2.6B 2.7B 2.8≈ 60 min🎮 3 games
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

5 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON B2 · EXPLAINER

Organic Chemistry: Homologous Series, Formulae, Naming and Isomers

There are millions of organic compounds, but they follow a handful of patterns. Once you know how to name and draw them, the whole of organic chemistry opens up.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Explore in 3D

Alkanes and isomers in 3D

Compare butane with its branched isomer 2-methylpropane: same atoms, different structure.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Carbon

Forms four covalent bonds; chains, branches and rings.

Formulae

Molecular, condensed, fully displayed.

Homologous series

Same functional group and general formula; similar chemistry; gradual physical change; differ by CH₂.

General formulae

Alkane CₙH₂ₙ₊₂; alkene CₙH₂ₙ; alcohol CₙH₂ₙ₊₁OH; acid CₙH₂ₙ₊₁COOH.

Stems

meth, eth, prop, but, pent, hex.

Endings

-ane, -ene, -anol, -anoic acid.

Isomers

Same molecular formula, different structure.

Saturated / unsaturated

Only single C–C bonds / contains C=C.

EXAM TIPS & COMMON MISTAKES

  • Count bonds: every carbon in a displayed formula must have exactly four.
  • Number the chain from the end that gives the lowest number to the branch or double bond.
  • To deduce the series from a formula: C and H only with CₙH₂ₙ₊₂ → alkane; CₙH₂ₙ → alkene.
  • For isomers, change the structure, not the formula, and check you have not drawn the same molecule twice.
Play & practise

Games

3 quick games on this lesson. Earn XP and badges as you play — your best score for each game is saved. Games are for practice and do not change your exam readiness. More games in the Chemistry Arcade.

Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Syllabus B 2.1

1. The number of covalent bonds formed by each carbon atom in an organic compound is

Answer: D. Carbon has four outer electrons.
Syllabus B 2.4

2. The general formula of the alkanes is

Answer: C. Saturated hydrocarbons.
Syllabus B 2.4

3. The molecular formula of the alkene with 4 carbon atoms is

Answer: D. CₙH₂ₙ: C₄H₈.
Syllabus B 2.5

4. Which is the functional group of the alcohols?

Answer: A. Hydroxyl group.
Syllabus B 2.6

5. The name of CH₃CH₂CH₃ is

Answer: B. Three carbons, single bonds.
Syllabus B 2.6

6. The name of CH₃CH₂COOH is

Answer: C. Three carbons including the COOH carbon.
Syllabus B 2.7

7. Which pair are structural isomers?

Answer: D. Both are C₄H₁₀.
Syllabus B 2.3

8. Members of a homologous series have

Answer: A. The same functional group gives similar chemistry.
Step 4 · Apply

Paper 2 practice — structured questions

Write full answers, then reveal the mark scheme and tick the points you earned (16 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 2 style · Organic chemistry

Question 1 [16 marks]

The compounds ethane, ethene, ethanol and ethanoic acid belong to different homologous series.

(a) (a) Define the term homologous series. [3]

MARK SCHEME — (a) (max 3)

(b) (b) State the general formula of the alkenes and the molecular formula of the alkene with 5 carbon atoms. [2]

MARK SCHEME — (b) (max 2)

(c) (c) Draw the fully displayed formulae of ethane and ethene. [4]

MARK SCHEME — (c) (max 4)

(d) (d) Name the functional group in ethanol and in ethanoic acid. [2]

MARK SCHEME — (d) (max 2)

(e) (e) Define structural isomerism and draw the two isomers of C₄H₁₀. [4]

MARK SCHEME — (e) (max 4)

(f) (f) Name the compound CH₃CH(CH₃)CH₃. [1]

MARK SCHEME — (f) (max 1)

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Sources

Where this topic appears in CSEC papers

Find these in your own past-paper booklets for extra timed practice. Items above are written in the style of these papers; any adapted from a specific question say so.