CSEC CHEMISTRY · SECTION B · LESSON B4

Alcohols and Alkanoic Acids: Properties, Fermentation and Reactions

Identifying alcohols, acids and esters by functional groups, how properties depend on the –OH and –COOH groups, the reactions of ethanol, fermentation, and the reactions of ethanoic acid.

Organic ChemistryB 3.5B 3.6B 3.7B 3.8B 3.9≈ 60 min🎮 3 games
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

5 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON B4 · EXPLAINER

Alcohols and Alkanoic Acids: Properties, Fermentation and Reactions

Rum, vinegar and the smell of ripe fruit all come from the same chemistry. A change in one functional group turns an alcohol into an acid and then into an ester.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Explore in 3D

Ethanol and ethanoic acid in 3D

Find the –OH and –COOH functional groups.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Alcohol

R–OH; neutral; soluble when short; reacts with sodium (H₂).

Alkanoic acid

R–COOH; weak acid; reacts with metals, bases, carbonates and alcohols.

Ester

R–COO–R′; sweet smelling; insoluble.

Hydrogen bonding

Explains solubility and higher boiling points.

Oxidation of ethanol

Acidified K₂Cr₂O₇ (orange → green) → ethanoic acid.

Dehydration of ethanol

Conc. H₂SO₄ or Al₂O₃ → ethene + water.

Fermentation

C₆H₁₂O₆ → 2C₂H₅OH + 2CO₂; yeast; 25–35 °C; anaerobic.

Esterification

Acid + alcohol ⇌ ester + water (conc. H₂SO₄).

EXAM TIPS & COMMON MISTAKES

  • Describe fermentation with conditions AND the equation (January 2026 emphasised equations with conditions).
  • For the oxidation test give the colour change of the oxidising agent.
  • Ethanoic acid is a WEAK acid: reactions are slower and its pH is higher than for HCl of the same concentration.
  • Name the catalyst for esterification: concentrated sulfuric acid.
Play & practise

Games

3 quick games on this lesson. Earn XP and badges as you play — your best score for each game is saved. Games are for practice and do not change your exam readiness. More games in the Chemistry Arcade.

Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Syllabus B 3.5

1. The functional group of an alkanoic (carboxylic) acid is

Answer: A. Carboxyl group.
Syllabus B 3.5

2. Which compound is an ester?

Answer: B. It contains the –COO– link.
Syllabus B 3.6

3. Ethanol is soluble in water because it

Answer: C. The –OH group is polar.
Syllabus B 3.7

4. The reaction of ethanol with sodium produces

Answer: D. 2C₂H₅OH + 2Na → 2C₂H₅ONa + H₂.
Syllabus B 3.7

5. Acidified potassium dichromate(VI) changes from orange to green when mixed with

Answer: A. Ethanol is oxidised.
Syllabus B 3.8

6. The gas produced during fermentation of glucose is

Answer: B. Limewater turns milky.
Syllabus B 3.8

7. Fermentation of glucose is carried out at about

Answer: C. Yeast enzymes work best in a warm range.
Syllabus B 3.9

8. Ethanoic acid reacts with sodium carbonate to give a salt, water and

Answer: D. Acid + carbonate.
Step 4 · Apply

Paper 2 practice — structured questions

Write full answers, then reveal the mark scheme and tick the points you earned (15 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 2 style · Alcohols and acids

Question 1 [15 marks]

Ethanol can be made by fermentation of glucose and by hydration of ethene.

(a) (a) Write a balanced equation for the fermentation of glucose. [2]

MARK SCHEME — (a) (max 2)

(b) (b) State two conditions needed for fermentation. [2]

MARK SCHEME — (b) (max 2)

(c) (c) Describe how ethanol can be separated from the fermented mixture. [2]

MARK SCHEME — (c) (max 2)

(d) (d) Describe what happens when sodium is added to ethanol and write an equation. [3]

MARK SCHEME — (d) (max 3)

(e) (e) Name the product formed and the colour change when ethanol is warmed with acidified potassium dichromate(VI). [2]

MARK SCHEME — (e) (max 2)

(f) (f) Write the equation for the reaction between ethanol and ethanoic acid and name the catalyst. [3]

MARK SCHEME — (f) (max 3)

(g) (g) Explain why ethanoic acid is classified as a weak acid. [1]

MARK SCHEME — (g) (max 1)

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Sources

Where this topic appears in CSEC papers

Find these in your own past-paper booklets for extra timed practice. Items above are written in the style of these papers; any adapted from a specific question say so.