CSEC CHEMISTRY · SECTION A · LESSON A17

Rates of Reaction: Factors, Collision Theory and Graphs

What rate of reaction means, how it is measured, how concentration, temperature, surface area and catalysts change it, why (collision theory), and how to interpret rate graphs.

Principles of ChemistryA 10.1A 10.2A 10.3A 10.4≈ 55 min🎮 3 games
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

5 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON A17 · EXPLAINER

Rates of Reaction: Factors, Collision Theory and Graphs

Why do we keep food in the fridge, crush tablets before swallowing them, and use catalysts in car exhausts? All of it is about controlling the speed of reactions.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Rate

Change in amount or concentration of reactant or product per unit time.

Measuring rate

Gas volume, mass loss, time for a mark to disappear.

Factors

Concentration/pressure, temperature, surface area, catalyst.

Collision theory

Rate depends on the number of SUCCESSFUL collisions per second.

Activation energy

Minimum energy for a successful collision.

Catalyst

Lowers the activation energy; not used up.

Graph

Steeper = faster; gradient = rate; flat = finished.

Fair test

Control all variables except the one being changed.

EXAM TIPS & COMMON MISTAKES

  • When explaining temperature, mention BOTH more frequent collisions AND more particles with energy ≥ activation energy.
  • Controlled variables must be things you keep constant, not the one you are changing.
  • Precautions must be specific actions (gloves, goggles, fume hood), not “be careful” or a hazard.
  • Draw a smooth best-fit line; joining each point earns no mark.
Play & practise

Games

3 quick games on this lesson. Earn XP and badges as you play — your best score for each game is saved. Games are for practice and do not change your exam readiness. More games in the Chemistry Arcade.

Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Syllabus A 10.1

1. The rate of a reaction can be measured by

Answer: C. Rate = change in amount per unit time.
Syllabus A 10.2

2. Which change increases the rate of the reaction between zinc and dilute acid?

Answer: D. A larger surface area gives faster collisions.
Syllabus A 10.3

3. A catalyst increases the rate of a reaction by

Answer: A. It provides an alternative pathway.
Syllabus A 10.3

4. The rate of a reaction increases with temperature mainly because

Answer: B. A larger fraction of collisions is successful.
Syllabus A 10.4

5. On a graph of volume of gas against time, the reaction has finished when the curve

Answer: C. No more gas is produced.
Syllabus A 10.4

6. Two experiments use the same mass of magnesium and excess acid at different temperatures. The final volumes of hydrogen are

Answer: D. The same amount of magnesium gives the same amount of gas.
Syllabus A 10.1

7. 48 cm³ of gas is collected in 60 s. The average rate is

Answer: A. 48 ÷ 60.
Syllabus A 10.2

8. Which of these should be a controlled variable when investigating how acid concentration affects rate with magnesium?

Answer: B. The same mass (surface area) of metal is used each time.
Step 4 · Apply

Paper 2 practice — structured questions

Write full answers, then reveal the mark scheme and tick the points you earned (15 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 2 style · Rates of reaction

Question 1 [15 marks]

Zinc reacts with dilute hydrochloric acid: Zn(s) + 2HCl(aq) → ZnCl₂(aq) + H₂(g). A student measures the volume of hydrogen produced in 2 minutes using acid of different concentrations.

(a) (a) Define rate of reaction. [2]

MARK SCHEME — (a) (max 2)

(b) (b) Draw a labelled diagram of apparatus to collect and measure the volume of hydrogen. [3]

MARK SCHEME — (b) (max 3)

(c) (c) State the manipulated, responding and two controlled variables. [4]

MARK SCHEME — (c) (max 4)

(d) (d) Explain, using collision theory, why increasing the concentration increases the rate. [3]

MARK SCHEME — (d) (max 3)

(e) (e) State one precaution to take and give a reason. [2]

MARK SCHEME — (e) (max 2)

(f) (f) Describe how the volume–time graph would differ if zinc powder were used instead of zinc granules. [1]

MARK SCHEME — (f) (max 1)

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Sources

Where this topic appears in CSEC papers

Find these in your own past-paper booklets for extra timed practice. Items above are written in the style of these papers; any adapted from a specific question say so.