CSEC CHEMISTRY · SECTION A · LESSON A16

Quantitative Electrolysis, Faraday’s Constant and Industrial Applications

Factors that affect the products of electrolysis, the Faraday constant, calculating the mass or volume of a product from current and time, and industrial electrolysis: electroplating, purification, aluminium and chlorine.

Principles of ChemistryA 9.8A 9.9A 9.10A 9.11≈ 55 min🎮 3 games
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

5 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON A16 · EXPLAINER

Quantitative Electrolysis, Faraday’s Constant and Industrial Applications

A gold-plated watch has only a thin layer of gold. Faraday’s constant lets us calculate exactly how much metal a current deposits in a given time.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Faraday constant

96 500 C/mol: charge on 1 mole of electrons.

Q

Q = I × t (C = A × s).

Moles of electrons

Q ÷ 96 500.

Moles of metal

Moles of electrons ÷ charge on the ion.

H₂ at cathode

2 e⁻ per H₂; V = n × 24 dm³.

O₂ at anode

4 e⁻ per O₂.

Aluminium

Al₂O₃ in molten cryolite; graphite anodes are replaced.

Electroplating

Object = cathode; plating metal = anode.

EXAM TIPS & COMMON MISTAKES

  • Convert time to SECONDS and write Q = It first.
  • Always state the electron:product mole ratio from the half-equation.
  • Give the final answer with units and sensible significant figures.
  • Explain the use of cryolite: to lower the melting point and save energy.
Play & practise

Games

3 quick games on this lesson. Earn XP and badges as you play — your best score for each game is saved. Games are for practice and do not change your exam readiness. More games in the Chemistry Arcade.

Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Syllabus A 9.9

1. The Faraday constant is approximately

Answer: A. 96 500 C/mol.
Syllabus A 9.10

2. A current of 0.50 A flows for 1 930 s. The quantity of electricity is

Answer: A. Q = 0.50 × 1 930.
Syllabus A 9.10

3. The charge required to deposit 1 mole of silver (Ag⁺ + e⁻ → Ag) is

Answer: B. One mole of electrons.
Syllabus A 9.10

4. The charge required to deposit 1 mole of copper (Cu²⁺) is

Answer: C. Two moles of electrons.
Syllabus A 9.11

5. In the extraction of aluminium, cryolite is added to

Answer: D. It dissolves the ore at a lower temperature.
Syllabus A 9.11

6. In electroplating a spoon with silver, the spoon is

Answer: A. The metal is deposited at the cathode.
Syllabus A 9.11

7. The graphite anodes in aluminium extraction must be replaced because they

Answer: B. C + O₂ → CO₂.
Syllabus A 9.10

8. The volume of hydrogen at rtp liberated by 0.020 mol of electrons is (molar volume 24 dm³)

Answer: B. 0.010 mol × 24.
Step 4 · Apply

Paper 2 practice — structured questions

Write full answers, then reveal the mark scheme and tick the points you earned (16 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 2 style · Faraday calculations

Question 1 [16 marks]

A current of 0.50 A is passed through copper(II) sulfate solution for 32 minutes 10 seconds (1 930 s) using copper electrodes. Cu = 63.5; F = 96 500 C/mol.

(a) (a) Calculate the quantity of electricity passed. [2]

MARK SCHEME — (a) (max 2)

(b) (b) Calculate the number of moles of electrons. [2]

MARK SCHEME — (b) (max 2)

(c) (c) Write the half-equation at the cathode and calculate the mass of copper deposited. [4]

MARK SCHEME — (c) (max 4)

(d) (d) State what happens to the anode and why the colour of the solution does not change. [3]

MARK SCHEME — (d) (max 3)

(e) (e) Explain why cryolite is used in the extraction of aluminium. [2]

MARK SCHEME — (e) (max 2)

(f) (f) Describe how an iron key could be plated with silver. [3]

MARK SCHEME — (f) (max 3)

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Sources

Where this topic appears in CSEC papers

Find these in your own past-paper booklets for extra timed practice. Items above are written in the style of these papers; any adapted from a specific question say so.