CSEC CHEMISTRY · SECTION A · LESSON A18

Energetics: Exothermic and Endothermic Reactions

Energy changes in reactions, exothermic and endothermic reactions, energy profile diagrams, bond breaking and making, and calculating heat changes from experiments.

Principles of ChemistryA 11.1A 11.2A 11.3≈ 50 min🎮 3 games
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

5 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON A18 · EXPLAINER

Energetics: Exothermic and Endothermic Reactions

A campfire releases heat, while a cold pack for an injury absorbs it. Both are chemical reactions, and their energy diagrams are mirror images.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Exothermic

Releases energy; temperature rises; ΔH negative; products lower in energy.

Endothermic

Absorbs energy; temperature falls; ΔH positive; products higher in energy.

Activation energy

Minimum energy needed to start the reaction.

Bonds

Breaking absorbs energy; making releases energy.

q = mcΔT

m = mass of water/solution (g); c = 4.2 J/g °C.

ΔH

q ÷ moles (convert J to kJ); negative if the temperature rises.

Heat loss

Makes the experimental ΔH smaller than the true value.

Catalyst

Lowers Eₐ; ΔH unchanged.

EXAM TIPS & COMMON MISTAKES

  • Draw the profile diagram with both Eₐ and ΔH arrows labelled.
  • Convert joules to kilojoules before dividing by moles.
  • Give ΔH its sign: negative if the temperature rose, positive if it fell.
  • Precaution for combustion experiments: draught shield and insulation to reduce heat loss.
Play & practise

Games

3 quick games on this lesson. Earn XP and badges as you play — your best score for each game is saved. Games are for practice and do not change your exam readiness. More games in the Chemistry Arcade.

Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Syllabus A 11.1

1. In an exothermic reaction the surroundings

Answer: C. Energy is released to the surroundings.
Syllabus A 11.1

2. Which process is endothermic?

Answer: D. The temperature falls.
Syllabus A 11.1

3. ΔH for an exothermic reaction is

Answer: A. The products have less energy.
Syllabus A 11.2

4. On an energy profile of an endothermic reaction the products are

Answer: B. Energy was absorbed.
Syllabus A 11.2

5. The activation energy is the

Answer: C. It is the energy barrier.
Syllabus A 11.3

6. The energy absorbed to heat 100 g of water by 5.0 °C (c = 4.2 J/g °C) is

Answer: D. 100 × 4.2 × 5.0.
Syllabus A 11.3

7. In 50 cm³ of HCl + 50 cm³ of NaOH (each 1.0 mol/dm³), the temperature rises by 6.5 °C. ΔH in kJ/mol is closest to

Answer: A. 2 730 J ÷ 0.050 mol = 54.6 kJ/mol.
Syllabus A 11.3

8. In an experiment to find the heat of combustion of a fuel, heat loss to the surroundings makes the result

Answer: B. Less heat reaches the water than was produced.
Step 4 · Apply

Paper 2 practice — structured questions

Write full answers, then reveal the mark scheme and tick the points you earned (15 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 2 style · Energetics

Question 1 [15 marks]

50.0 cm³ of 1.00 mol/dm³ sodium hydroxide at 25.0 °C is added to 50.0 cm³ of 1.00 mol/dm³ hydrochloric acid at 25.0 °C in a polystyrene cup. The highest temperature reached is 31.5 °C. Take the density of the solution as 1.00 g/cm³ and c = 4.2 J/g °C.

(a) (a) State whether the reaction is exothermic or endothermic, with a reason. [2]

MARK SCHEME — (a) (max 2)

(b) (b) Calculate the heat energy transferred to the solution. [3]

MARK SCHEME — (b) (max 3)

(c) (c) Calculate the number of moles of acid that reacted. [2]

MARK SCHEME — (c) (max 2)

(d) (d) Calculate the enthalpy change of neutralisation in kJ/mol. [3]

MARK SCHEME — (d) (max 3)

(e) (e) Sketch an energy profile diagram for this reaction. [3]

MARK SCHEME — (e) (max 3)

(f) (f) State one source of error and one improvement. [2]

MARK SCHEME — (f) (max 2)

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Sources

Where this topic appears in CSEC papers

Find these in your own past-paper booklets for extra timed practice. Items above are written in the style of these papers; any adapted from a specific question say so.