CSEC CHEMISTRY · SECTION B · LESSON B6

Polymers: Addition and Condensation Polymerisation

What polymers are, addition polymerisation of alkenes (poly(ethene), PVC), condensation polymerisation (nylon, polyesters), natural polymers, uses and environmental problems.

Organic ChemistryB 4.1B 4.2B 4.3≈ 50 min🎮 3 games
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

5 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON B6 · EXPLAINER

Polymers: Addition and Condensation Polymerisation

Plastic bags, bottles, nylon ropes and even the proteins in your body are polymers: very long molecules built from small repeating units.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Explore in 3D

Monomer and polymer in 3D

Compare the ethene monomer with a section of a poly(ethene) chain.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Polymer

Macromolecule made from 50 or more monomers.

Monomer

Small repeating unit.

Addition

Unsaturated monomer (C=C); double bond opens; only polymer formed.

Examples (addition)

Poly(ethene), poly(propene), PVC.

Condensation

Two functional groups per monomer; water lost.

Examples (condensation)

Nylon (polyamide), Terylene (polyester), proteins.

Natural polymers

Proteins, starch, cellulose, rubber.

Environment

Non-biodegradable; toxic when burnt; recycle.

EXAM TIPS & COMMON MISTAKES

  • Define polymer with the words MACROMOLECULE and MONOMERS and a large number (50 or more).
  • Draw the repeating unit in brackets with a subscript n.
  • Name the type of polymerisation and give a reason (small molecule lost or not).
  • Mention at least one environmental problem and one solution.
Play & practise

Games

3 quick games on this lesson. Earn XP and badges as you play — your best score for each game is saved. Games are for practice and do not change your exam readiness. More games in the Chemistry Arcade.

Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Syllabus B 4.1

1. A polymer is a

Answer: A. Very large molecule from repeating units.
Syllabus B 4.2

2. The monomer used to make poly(ethene) is

Answer: B. Addition polymerisation.
Syllabus B 4.2

3. In addition polymerisation

Answer: C. Only the polymer forms.
Syllabus B 4.2

4. Nylon is formed by

Answer: D. Water is lost when it forms.
Syllabus B 4.2

5. Which is a natural condensation polymer?

Answer: A. Amino acids joined by amide links.
Syllabus B 4.3

6. PVC is used to make

Answer: B. Poly(chloroethene).
Syllabus B 4.2

7. Polyesters are formed from a diol and a

Answer: C. Ester links form.
Syllabus B 4.3

8. A major environmental problem of most synthetic polymers is that they are

Answer: D. They persist in the environment.
Step 4 · Apply

Paper 2 practice — structured questions

Write full answers, then reveal the mark scheme and tick the points you earned (15 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 2 style · Polymers

Question 1 [15 marks]

Polyethene is an addition polymer and nylon is a condensation polymer.

(a) (a) Define the term polymer. [2]

MARK SCHEME — (a) (max 2)

(b) (b) State the type of polymerisation used to make polyethene and name the monomer. [2]

MARK SCHEME — (b) (max 2)

(c) (c) Draw the structure of the monomer and the repeating unit of polyethene. [3]

MARK SCHEME — (c) (max 3)

(d) (d) State two differences between addition and condensation polymerisation. [2]

MARK SCHEME — (d) (max 2)

(e) (e) State one use of poly(ethene) and one use of nylon. [2]

MARK SCHEME — (e) (max 2)

(f) (f) Discuss two environmental problems caused by plastics and suggest a solution to each. [4]

MARK SCHEME — (f) (max 4)

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Sources

Where this topic appears in CSEC papers

Find these in your own past-paper booklets for extra timed practice. Items above are written in the style of these papers; any adapted from a specific question say so.