CSEC CHEMISTRY · SECTION A · LESSON A3

Solubility and Separation Techniques

How temperature affects the solubility of solids, and how to choose and describe filtration, evaporation, crystallisation, simple and fractional distillation, chromatography and the separating funnel, including sugar extraction.

Principles of ChemistryA 2.4A 2.5A 2.6≈ 50 min🎮 3 games
Before you start

By the end of this lesson you can…

Step 1 · Watch

Explainer video

5 narrated scenes. Press play, listen and read along — the points appear as they are explained. Use ‹ Prev / Next › or the scene bar to jump to any scene.

LESSON A3 · EXPLAINER

Solubility and Separation Techniques

Sugar cane is crushed in the field and ends up as sparkling crystals in your kitchen. Along the way, the chemist uses almost every separation technique in the book.

Narration uses your device’s built-in voice. No sound? Switch to “Captions only” — the captions advance on their own.

Step 2 · Read

Key notes

Copy these into your notebook in your own words — that is how they stick.

Solubility

Mass dissolving in 100 g of water at a stated temperature; most solids more soluble when hot.

Filtration

Insoluble solid from liquid: residue and filtrate.

Evaporation / crystallisation

Recover a dissolved solid; crystallise to get pure crystals.

Simple distillation

Solvent from a solution; condense the vapour.

Fractional distillation

Miscible liquids with different boiling points.

Chromatography

Rf = distance by spot ÷ distance by solvent; use a pencil line.

Separating funnel

Immiscible liquids: run off the denser one first.

Sugar extraction

Crush → lime → filter → vacuum evaporation → crystallise → centrifuge.

EXAM TIPS & COMMON MISTAKES

  • Always name the property that allows each separation (particle size, boiling point, solubility, density).
  • In diagrams: label the condenser water IN at the bottom and OUT at the top, and the thermometer bulb at the vapour outlet.
  • The chromatography baseline is drawn in pencil, and must be above the solvent level.
  • For crystals say “cool slowly” to give larger crystals.
Play & practise

Games

3 quick games on this lesson. Earn XP and badges as you play — your best score for each game is saved. Games are for practice and do not change your exam readiness. More games in the Chemistry Arcade.

Step 3 · Practise

Paper 1 practice — multiple choice

8 items modelled on real CSEC Paper 1 questions. Choose one answer for each, then check. Aim for 80% or better. Work each item on paper first.

Syllabus A 2.5

1. To separate sand from a mixture of sand and water you would use

Answer: A. Sand is insoluble and is trapped by the filter paper.
Syllabus A 2.5

2. Pure water can be obtained from sea water by

Answer: B. Water boils and condenses, leaving salt behind.
Syllabus A 2.5

3. Ethanol (b.p. 78 °C) and water (b.p. 100 °C) are best separated by

Answer: C. The liquids are miscible with different boiling points.
Syllabus A 2.5

4. Oil and water can be separated using a

Answer: D. They are immiscible and have different densities.
Syllabus A 2.5

5. In paper chromatography the starting line is drawn in pencil because pencil

Answer: A. Ink would dissolve and move with the solvent.
Syllabus A 2.5

6. A spot moves 3.0 cm while the solvent front moves 6.0 cm. The Rf value is

Answer: A. Rf = 3.0 ÷ 6.0 = 0.50.
Syllabus A 2.6

7. In the extraction of sugar from cane, lime is added to

Answer: B. Impurities are precipitated and then filtered off.
Syllabus A 2.6

8. Evaporation under reduced pressure is used in sugar manufacture so that the

Answer: C. Reduced pressure lowers the boiling point.
Step 4 · Apply

Paper 2 practice — structured questions

Write full answers, then reveal the mark scheme and tick the points you earned (15 marks in total). Show all your working — method marks count. Your answers are saved on this device.

Paper 2 style · Separation

Question 1 [15 marks]

A student has a mixture of sand, salt and water and also a mixture of ethanol and water.

(a) (a) Describe how the student can obtain dry sand and solid salt from the first mixture. [5]

MARK SCHEME — (a) (max 5)

(b) (b) Name the technique used to separate ethanol from water and state the property used. [2]

MARK SCHEME — (b) (max 2)

(c) (c) Draw a labelled diagram of the apparatus used for simple distillation. [4]

MARK SCHEME — (c) (max 4)

(d) (d) A chromatogram shows a spot 4.5 cm from the baseline when the solvent front is 9.0 cm. Calculate the Rf value. [2]

MARK SCHEME — (d) (max 2)

(e) (e) Explain why potassium nitrate crystals form when a hot saturated solution cools. [2]

MARK SCHEME — (e) (max 2)

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Sources

Where this topic appears in CSEC papers

Find these in your own past-paper booklets for extra timed practice. Items above are written in the style of these papers; any adapted from a specific question say so.